Balancing equations is harder because you can't really just plug and chug. You have to think about what steps are most intelligent. There's kind of a methodical pattern though.
For example, here's a step-by-step way to do the reaction ember was talking about.
We start with:
_Rb + _RbNO3 -> _Rb2O + _N2
There are 3 elements to be concerned with: Rb, N, and O. Right now, the status is:
Rb - 2 on reactant side, 2 on product side (balanced)
N - 1 on reactant side, 2 on product side (unbalanced)
O - 3 on reactant side, 1 on product side (unbalanced)
We can make adjustments by adding numbers to the _, which multiplies all the elements in the compound that it prefixes. A good rule of thumb is to try to make small adjustments first.
So let's try to balance the N. Replace the 2nd _ with a 2, the equation is then:
_Rb + 2RbNO3 -> _Rb20 + _N2
Rb - 3 on left, 2 on right (unbalanced)
N - 2 on left, 2 on right (balanced)
O - 6 on left, 1 on right (unbalanced)
To balance the Rb, we would have to add prefixes to both sides since 2 and 3 are relatively prime. So let's balance the O now because that's easier. We can do that by putting a 6 in the first _ on the product side. Rb20 has 1 O, so 6Rb20 will have 6 O's.
As a side effect, the Rb2 is also multiplied by 6, so now we have 12 Rb's on the right.
Now we have:
_Rb + 2RbNO3 -> 6Rb20 + _N2
Rb - 2 on left, 12 on right (unbalanced)
N - 2 on left, 2 on right (balanced)
O - 6 on left, 6 on right (balanced)
Since the first symbol on the reactant side is Rb alone, we can prefix it without affecting the amounts of other elements. So all we have to do is multiply it by 10 to increase the number of Rb's on the left by 10.
And we end up with:
10Rb + 2RbNO3 -> 6Rb20 + N2
(12 Rb's, 2 N's and 6 O's)
In short, write down the elements and how many of each are on each side. Then try to do the smallest possible change that will balance an additional element, and go from there. Sometimes you'll have to do larger changes and cross out stuff a lot, but this works for most simpler reactions.
See if you can apply this to the other problems. Hope that helps!